When Pokémon Worlds Collide! : Season 10 Episode 3
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Aired: September 28th, 2006
While searching for Pikachu, Ash and Brock run into a new rival named Paul, who challenges Ash to a battle, but Ash can't compete without Pikachu; Dawn and Piplup meet Ash and Brock, and together they try to rescue Pikachu from Team Rocket.